Name: AAPH
Rating: 5 (10 reviews)

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HIT ID:HIT212089110
Cas No:2997-92-4
常用名:AAPH
IUPAC:2-[2-(1-carbamimidoyl-1-methylethyl)diazen-1-yl]-2-methylpropanimidamide dihydrochloride
IUPAC:2-[2-(1-carbamimidoyl-1-methylethyl)diazen-1-yl]-2-methylpropanimidamide dihydrochloride
InChI key:LXEKPEMOWBOYRF-UHFFFAOYSA-N

分子式:C8H20Cl2N6
分子量:271.19
氢键供体数 (HBD):4
氢键受体数 (HBA):6
LogP:-0.31975856
SMILES:Cl.Cl.CC(C)(N=NC(C)(C)C(N)=N)C(N)=N |w:5.2|
SMILES:Cl.Cl.CC(C)(N=NC(C)(C)C(N)=N)C(N)=N |w:5.2|

AAPH is a water-soluble azo compound which is used extensively as a free radical generator, often in the study of lipid peroxidation and the characterization of antioxidants.[1],[2],[3],[4] Decomposition of AAPH produces molecular nitrogen and 2 carbon radicals. The carbon radicals may combine to produce stable products or react with molecular oxygen to give peroxyl radicals. The half-life of AAPH is about 175 hours (37°C at neutral pH), making the rate of free radical generation essentially constant during the first several hours in solution.[5] While AAPH may be used effectively for lipid peroxidation in aqueous dispersions of fatty acids, other radical generators may be better suited for peroxidation studies in lipid micelles or membranes.[6],[7]

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